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Zemo disguises himself as a psychiatrist and while interviewing Barnes he uses the book he stole to brainwash Barnes and send him on a rampage. The four are taken away by police and Barnes is placed under arrest. CIA agent Sharon Carter informs Rogers of Barnes' location so he and Wilson attempt to bring him into custody but T'Challa arrives and tries to kill Barnes. Barnes is spotted in the security footage and T'Chaka's son T'Challa adopts his Black Panther mantle and vows to kill Barnes. At a United Nations conference in Vienna, King T'Chaka is killed by a bomb while giving a speech. Meanwhile, Helmut Zemo kills Barnes' old HYDRA commander and steals his brainwashing book. Stark, Romanoff, James Rhodes and Vision agree with it while Rogers and Wilson disagree. The Secretary of State Thaddeus Ross displays the Sokovia Accords to Tony Stark and the Avengers, which have been passed by the United Nations and says that the United Nations will control the team. Rumlow attempts to kill Rogers by exploding himself but Maximoff accidentally sends him spiralling into a building, causing many casualties. Steve Rogers, Natasha Romanoff, Sam Wilson and Wanda Maximoff stop Brock Rumlow from stealing a biological weapon in Lagos. In the present day 2016, it has been a year since Ultron's destruction. In 1991, James "Bucky" Barnes is sent from a HYDRA base in Siberia to attack a car carrying vials of the Super Soldier Serum. Helicarriers (Appears on a computer screen, TV, or hologram only) Spider-Man's Utility Belt (First appearance).Iron Man Armor MK XLVI (First appearance).Tony Stark's Sunglasses (First appearance).Spider-Man's Spider-Signal (First appearance).Spider-Man's Web-Shooters (First appearance).War Machine Armor MK III (First appearance).Super-Soldier Serum (Only in flashback).Winter Soldier's Bionic Arm (Destruction).Memory Supression Device (Only in flashback).Institute for Infectious Diseases Building.
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Crossbones' mercenaries (Only appearance).Spider-Man (Peter Parker) (First appearance).Black Panther (Prince T'Challa) (First appearance).Joint Counter Terrorist Centre (First appearance).Black Widow (Natasha Romanoff) (Leaves team).Winter Soldier (Bucky Barnes) (Main story and flashback).Iron Man (Tony Stark) (Rejoins the Avengers).Captain America (Steve Rogers) (Leaves the Avengers).